804552-07-6

Basic information

• Product Name: [(2S,4S,5S,6S)-6-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester
• Synonyms: [(2S,4S,5S,6S)-6-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester
• CAS NO: 804552-07-6
• Molecular Weight: 524.77
• Mol File: 804552-07-6.mol

Chemical Properties

• CAS DataBase Reference: [(2S,4S,5S,6S)-6-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: [(2S,4S,5S,6S)-6-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester(804552-07-6)
• EPA Substance Registry System: [(2S,4S,5S,6S)-6-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-4-(tert-butyl-dimethyl-silanyloxy)-2-methoxy-5-methyl-tetrahydro-pyran-2-yl]-acetic acid methyl ester(804552-07-6)

Safety Data

• Hazardous Substances Data: 804552-07-6(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 804551-94-8 (4R,5R,6R)-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-acetic acid methyl ester 
• 60656-87-3 benzyloxyacetoaldehyde 
• 804551-90-4 (2R,3S)-4-benzyloxy-3-methoxy-2-methyl-butyraldehyde 
• 804552-00-9 (5S,6S)-7-benzyloxy-6-hydroxy-5-methyl-hept-3-enoic acid methyl ester 
• 804552-01-0 (5S,6S)-7-benzyloxy-6-methoxy-5-methyl-hept-3-enoic acid methyl ester 
• 804551-88-0 (2R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester 
• 804552-02-1 (2R,4S,5S)-4-((1S,2S)-3-Benzyloxy-2-methoxy-1-methyl-propyl)-5-methyl-3,7-dioxa-bicyclo[4.1.0]heptane-2-carboxylic acid methyl ester 
• 804551-92-6 (5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-5-methyl-4-oxo-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester 
• 804552-05-4 (4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-hydroxy-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester 
• 804551-89-1 (2R,3S,4R,5S)-[5-benzyloxymethyl-3-(dimethyl-phenyl-silanyl)-4-methyl-tetrahydro-furan-2-yl]-acetic acid methyl ester 
• 804551-93-7 (4R,5R,6R)-6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyldimethyl-silanyloxy)-5-methyl-5,6-dihydro-2H-pyran-2-carboxylic acid methyl ester 
• 804552-06-5 (4R,5R,6R)-1-{6-[(1R,2S)-3-benzyloxy-2-methoxy-1-methyl-propyl]-4-(tert-butyl-dimethyl-silanyloxy)-5-methyl-5,6-dihydro-4H-pyran-2-yl}-2-diazo-ethanone 

Relevant articles and documents

Total synthesis of callipeltoside A

(Chemical Equation Presented) A convergent total synthesis of cytotoxic marine macrolide callipeltoside A is described. The synthesis highlights two stereoselective [4 + 2] annulations for the preparation of associated pyran rings.