80502-02-9

Upstream product

• 22331-19-7 3-O-benzyl-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose 
• 19877-13-5 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-enofuranose 

Downstream Products

• 80485-57-0 methyl 3-O-benzyl-5,6-dideoxy-2-O-<(methylthio)thiocarbonyl>-α,β-D-xylo-hex-5-enofuranoside 
• 80502-04-1 methyl 3-O-benzyl-2,5,6-trideoxy-α,β-D-threo-hex-5-enofuranoside 
• 80485-59-2 3-O-benzyl-2,5,6-trideoxy-D-threo-hex-5-enofuranose 
• 80502-06-3 (6R,7R)-6-(benzyloxy)-7-hydroxynonan-2-one 

Relevant academic research and scientific papers

Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 2. Synthesis of (+)-exo-Brevicomin

The hydrated, acyclic form of (+)-exo-brevicomin indicates that the chirality of the molecule resides in a D-threo glycol segment such as that found at C3 and C4 of D-glucose.Accordingly, "acyclic transfer" of this portion of the sugar into a suitable pre