80502-04-1

Upstream product

• 1579954-57-6 C₁₇H₃₄O₄Si 
• 1579954-56-5 (4R,Z)-4-benzyloxy-6-(tert-butyldimethylsilyloxy)-1-(tetrahydropyran-2-yloxy)-hex-2-ene 
• 1579954-59-8 (3R,E)-3-(benzyloxy)-6-(tetrahydropyran-2-yloxy)hex-4-en-1-ol 
• 67-56-1 methanol 
• 1579954-58-7 (3R,Z)-3-(benzyloxy)-6-(tetrahydropyran-2-yloxy)-hex-4-enal 
• 1579954-60-1 6-(tert-butyldimethylsilyloxy)-1-(tetrahydropyran-2-yloxy)-hex-2-en-4-ol 
• 1579954-61-2 (4R,E)-4-(benzyloxy)-6-(tert-butyldimethylsilyloxy)-1-(tetrahydropyran-2-yloxy)-2-hexene 
• 1579954-62-3 (3R,E)-3-(Benzyloxy)-6-(tetrahydropyran-2-yloxy)-hex-4-enal 
• 1579954-52-1 6-(tert-butyldimethylsilyloxy)-1-(tetrahydropyran-2-yloxy)-hex-2-yn-4-ol 
• 1579954-53-2 6-(tert-butyldimethylsilyloxy)-1-(tetrahydropyran-2-yloxy)hex-2-yn-4-one 
• 1579954-54-3 (R)-6-(tert-butyldimethylsilyloxy)-1-(tetrahydropyran-2-yloxy)-hex-2-yn-4-ol 
• 80502-02-9 methyl 3-O-benzyl-5,6-dideoxy-α,β-D-xylo-hex-5-enofuranoside 
• 19877-13-5 3-O-benzyl-5,6-dideoxy-1,2-O-isopropylidene-α-D-xylo-hex-5-enofuranose 
• 22331-19-7 3-O-benzyl-1,2-O-isopropylidene-5,6-di-O-mesyl-α-D-glucofuranose 

Downstream Products

• 80485-59-2 3-O-benzyl-2,5,6-trideoxy-D-threo-hex-5-enofuranose 
• 80502-06-3 (6R,7R)-6-(benzyloxy)-7-hydroxynonan-2-one 

Relevant academic research and scientific papers

Synthesis of 2-deoxy-l-ribose via palladium(ii)-catalyzed cyclization

We present a total synthesis of 2-deoxy-L-ribose through intramolecular palladium(II)-catalyzed cyclization of aldehyde via an unstable hemiacetal intermediate as the key step.

Synthetic Routes to 6,8-Dioxabicyclooctyl Pheromones from D-Glucose Derivatives. 2. Synthesis of (+)-exo-Brevicomin

The hydrated, acyclic form of (+)-exo-brevicomin indicates that the chirality of the molecule resides in a D-threo glycol segment such as that found at C3 and C4 of D-glucose.Accordingly, "acyclic transfer" of this portion of the sugar into a suitable pre