80525-60-6

Basic information

• Product Name: Ethanol, 2,2'-[[1-[(phenylmethoxy)methyl]-1,2-ethanediyl]bis(oxy)]bis-
• CAS NO: 80525-60-6
• Molecular Formula: C14H22O5
• Molecular Weight: 270.326
• Mol File: 80525-60-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Ethanol, 2,2'-[[1-[(phenylmethoxy)methyl]-1,2-ethanediyl]bis(oxy)]bis-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanol, 2,2'-[[1-[(phenylmethoxy)methyl]-1,2-ethanediyl]bis(oxy)]bis-(80525-60-6)
• EPA Substance Registry System: Ethanol, 2,2'-[[1-[(phenylmethoxy)methyl]-1,2-ethanediyl]bis(oxy)]bis-(80525-60-6)

Safety Data

• Hazardous Substances Data: 80525-60-6(Hazardous Substances Data)

Upstream product

• 13071-59-5 3-benzyloxypropan-1,2-diol 
• 79-11-8 chloroacetic acid 
• 80525-59-3 4-[(benzyloxy)methyl]-3,6-dioxaoctane-1,8-dicarboxylic acid 

Downstream Products

• 94650-69-8 1,14-Bis-7-benzyloxymethyl-3,6,9,12-tetraoxatetradecane 
• 85725-87-7 11-benzyloxymethyl-2,3-benzo-18-crown-6 
• 76377-04-3 2-Benzyloxymethyl-1,4,7,10,13,16-hexacyclooctadecan 
• 86210-61-9 Toluene-4-sulfonic acid 6,7,9,10,12,13,15,16,18,19-decahydro-5,8,11,14,17,20-hexaoxa-benzocyclooctadecen-12-ylmethyl ester 
• 91472-18-3 7-<(benzyloxy)methyl>-3,6,9,12-tetraoxa-1,14-tetradecanediol 
• 75507-17-4 benzyl 2,4,7,10,13-pentaoxacyclopentadecan-2-ylmethyl ether 
• 94650-70-1 dimesylate of 7-benzyloxymethyl-3,6,9,12-tetraoxa-1,14-tetradecanediol 
• 94650-71-2 N-Benzyl-8-benzyloxymethyl-4,7,10,13-tetraoxa-1-azacyclopentadecane 
• 94650-72-3 8-Benzyloxymethyl-4,7,10,13-tetraoxa-1-azacyclopentadecane 
• 137743-90-9 {12-[4-Decyl-2-(diethoxy-phosphoryl)-phenoxymethyl]-2,5,8,11,14,17,20,23-octaoxa-bicyclo[22.3.1]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-trien-28-yloxy}-acetic acid tert-butyl ester 
• 137743-84-1 {12-[4-Decyl-2-(ethoxy-hydroxy-phosphoryl)-phenoxymethyl]-2,5,8,11,14,17,20,23-octaoxa-bicyclo[22.3.1]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-trien-28-yloxy}-acetic acid 
• 137743-89-6 [12-(Toluene-4-sulfonyloxymethyl)-2,5,8,11,14,17,20,23-octaoxa-bicyclo[22.3.1]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-trien-28-yloxy]-acetic acid tert-butyl ester 
• 137743-87-4 (12-Benzyloxymethyl-2,5,8,11,14,17,20,23-octaoxa-bicyclo[22.3.1]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-trien-28-yloxy)-acetic acid tert-butyl ester 
• 137743-86-3 12-Benzyloxymethyl-2,5,8,11,14,17,20,23-octaoxa-bicyclo[22.3.1]octacosa-1⁽²⁷⁾,24⁽²⁸⁾,25-trien-28-ol 

Relevant articles and documents

Synthesis of lipophilic lariat ethers with pendant N-(X)sulfonyl carboxamide groups

Synthetic routes to sixteen lipophilic lariat ether N-(X)sulfonyl carboxamides with X = trifluoromethyl, methyl, phenyl, and p-nitrophenyl are described. For this new family of proton-ionizable lariat ethers in which the acidity can be 'tuned' by X group variation, the ring size is systematically varied from 12-crown-4 to 14-crown-4 to 15-crown-5 to 18-crown-6.

Phase-Transfer-Catalyzed Synthesis of Oligoethylene Glycols and Derivatives

An efficient, two-step synthetic method for the addition of ethyleneoxy units to diols is reported.Reaction of HOROH with Cl(CH2CH2O)nTHP and 50percent aqueous NaOH in the presence of a phase-transfer catalyst gives THP(OCH2CH2)nORO(CH2CH2O)nTHP from which the protecting groups are readily removed to provide H(OCH2CH2)nORO(CH2CH2O)n in good-to-excellent yields.The influence of reactant diol structure upon yield has been determined.