80606-06-0

Basic information

• Product Name: 4-Methyl-2-pentanonoxim-pikrat
• Synonyms: 4-Methyl-2-pentanonoxim-pikrat
• CAS NO: 80606-06-0
• Molecular Weight: 326.266
• Mol File: 80606-06-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Methyl-2-pentanonoxim-pikrat(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Methyl-2-pentanonoxim-pikrat(80606-06-0)
• EPA Substance Registry System: 4-Methyl-2-pentanonoxim-pikrat(80606-06-0)

Safety Data

• Hazardous Substances Data: 80606-06-0(Hazardous Substances Data)

Upstream product

• 108-10-1 4-methyl-2-pentanone 
• 88-88-0 2,4,6-trinitrochlorobenzene 
• 105-44-2 4-methyl-pentan-2-one oxime 

Downstream Products

• 20722-58-1 N-Isobutyl-N-(2,4,6-trinitro-phenyl)-acetamide 

Relevant articles and documents

Wanderungstendenzen cyclischer, polycyclischer und methylverzweigter Alkylreste bei der Beckmann-Umlagerung

The migration aptitudes of polycyclic bridgehead groups, cycloalkyl groups as well as of β-, γ- and δ-branched alkyl groups in the Chapman variant of the Beckmann rearrangement were determined.From these data it is concluded that at transition state 2 the migrating group is not resembling a planarised carbenium ion R+, but rather a pentacoordinated carbonium ion structure.Because only small geometrical changes occur in the migrating group vertical stabilisation of charge at transition state is believed to have significant influence on the migration aptitudes.