80667-85-2

Upstream product

• 80680-58-6 methyl 3-O-benzyl-4,6-O-benzylidene-2-O-(N-imidazole-1-sulfonyl)-α-D-glucopyranoside 
• 2774-19-8 methyl 3-O-benzyl-4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 80667-89-6 (4aR,6S,8R,8aS)-8-(benzyloxy)-6-methoxy-2-phenylhexahydropyrano[3,2-d][1,3]dioxine 

Relevant academic research and scientific papers

Design and reactivity of organic functional groups - Preparation and nucleophilic displacement reactions of imidazole-1-sulfonates (imidazylates)

Imidazole-1-sulfonate, a new type of leaving group by remote activation, allows facile S(N)2 substitution reactions at sterically crowded centers with various nucleophiles under mild conditions. It could be easily prepared from alcohols with cheap reagent

DESIGN AND REACTIVITY OF ORGANIC FUNCTIONAL GROUPS: IMIDAZOLYLSULFONATE (IMIDAZYLATE) - AN EFFICIENT AND VERSATILE LEAVING GROUP

The preparation and reactivity of the novel imidazolylsulfonate group is described.