80697-72-9

Basic information

• Product Name: iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene
• Synonyms: iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene
• CAS NO: 80697-72-9
• Molecular Weight: 915.469
• Mol File: 80697-72-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene(CAS DataBase Reference)
• NIST Chemistry Reference: iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene(80697-72-9)
• EPA Substance Registry System: iron(II) tetraphenylporphyrin (thiophthalimido)chlorocarbene(80697-72-9)

Safety Data

• Hazardous Substances Data: 80697-72-9(Hazardous Substances Data)

Upstream product

• 16456-81-8 meso-tetraphenylporphyrin iron(III) chloride 
• 133-07-3 2-trichloromethylthio-1H-isoindole-1,3(2H)-dione 

Downstream Products

• 67583-11-3 thiocarbonyl(5,10,15,20-tetraphenylporphyrinato)iron(II) 

Relevant articles and documents

A new route to thiocarbonyl-iron complexes: Preparation of FeII[porphyrin][C(Cl)SR] carbene complexes and their conversion to FeII[porphyrin][CS] complexes

The reaction of trichloromethyl-thioalkyl compounds including the widely used fungicides Captan and Folpet with iron(II) porphyrins in the presence of a reducing agent in excess leads to the formation of new carbene complexes, Fe[porphyrin][C(Cl)SR], whose stabilities are strongly dependent on the nature of the R substituent. Upon treatment by a catalytic amount of FeCl2 or CuCl2, some of them are decomposed into thiocarbonyliron(II)-porphyrin complexes, Fe[porphyrin][CS], in nearly quantitative yields. Various Fe[porphyrin][CS][L] complexes have thus been obtained by this method and characterized by UV-visible, IR, and 1H and 13C NMR spectroscopy. They are very stable to dioxygen and nucleophiles but react with primary amines R′NH2 in excess to give the Fe[porphyrin][CNR′][R′NH2] complexes. Reduction of C6H5SCHCl2 by iron(II) tetraphenylporphyrin, Fe[TPP], leads to the Fe[TPP][CHSC6H5] complex, which is the first example of an iron(II) porphyrin complex bearing a secondary CHR carbene.