80699-65-6

Basic information

• Product Name: Silane, trimethyl[(3,5,5-trimethyl-1,3-cyclohexadien-1-yl)oxy]-
• CAS NO: 80699-65-6
• Molecular Formula: C12H22OSi
• Molecular Weight: 210.392
• Mol File: 80699-65-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[(3,5,5-trimethyl-1,3-cyclohexadien-1-yl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[(3,5,5-trimethyl-1,3-cyclohexadien-1-yl)oxy]-(80699-65-6)
• EPA Substance Registry System: Silane, trimethyl[(3,5,5-trimethyl-1,3-cyclohexadien-1-yl)oxy]-(80699-65-6)

Safety Data

• Hazardous Substances Data: 80699-65-6(Hazardous Substances Data)

Upstream product

• 78-59-1 3,5,5-Trimethylcyclohex-2-en-1-one 
• 7449-74-3 N-methyl-N-trimethylsilylacetamide 
• 75-77-4 chloro-trimethyl-silane 

Downstream Products

• 79734-43-3 3,5,5-trimethyl-4-[(E)-3-oxo-1-butenyl]-2-cyclohexen-1-one 

Relevant articles and documents

Silazanes/catalytic bases: Mild, powerful and chemoselective agents for the preparation of enol silyl ethers from ketones and aldehydes

We have developed an efficient method for the preparation of enol silyl ethers using novel agents, silazanes together with NaH or DBU catalyst, wherein TMS and TBDMS groups were smoothly and chemoselectively introduced into ketones and aldehydes under mil

New Synthesis of Megastigma-4,6,8-trien-3-ones, 3-Hydroxy-β-ionol, 3-Hydroxy-β-ionone, 5,6-Epoxy-3-hydroxy-β-ionol, and 3-Oxo-α-ionol

The Lewis acid-catalyzed reaction of 1-trimethylsiloxy-1,3-cyclohexadienes with aldehydes and trialkyl orthoformates afforded the corresponding 4-substituted 2-cyclohexenones.A new reaction of 2,4,6-trienones with m-chloroperbenzoic acid followed by the reduction with zinc in acetic acid gave 7-hydroxy-3,5-dienones.Utilizing these efficient reactions, megastigma-4,6,8-trien-3-ones, 3-hydroxy-β-ionol, 3-hydroxy-β-ionone, 5,6-epoxy-3-hydroxy-β-ionol, and 3-oxo-α-ionol were successfully synthesized.