80729-06-2Relevant academic research and scientific papers
Intramolecular Photocycloaddition of the 3-(3-Butenyloxy)-2-cyclohexenone System
Umehara, Takashi,Inouye, Yoshinobu,Kakisawa, Hiroshi
, p. 3492 - 3494 (1981)
The irradiation of 5,5-dimethyl-3-(4-methyl-3-pentenyloxy)-2-cyclohexenone gave regioselectively, 6,6,10,10-tetramethyl-2-oxatricyclo1,5>undecan-8-one, while, that of 5,5-dimethyl-3--2-cyclohexenone afforded, regio- and stereoselectively, 1,5,5-trimethyl-8-oxatetracyclo2,7.01,5>tetradecan-3-one.
PALLADIUM DICHLORIDE-PROMOTED CYCLIZATIONS OF 1,5-DIENES. A NEW METHOD FOR FORMING CYCLOHEXENES.
Overman, Larry E.,Renaldo, Alfred F.
, p. 2235 - 2238 (2007/10/02)
1,5-Hexadienes, which are substituted with electron-withdrawing groups at carbon-3, undergo regioselective rearrangement to cyclohexenes upon treatment with palladium dichloride.
