Bulletin of the Chemical Society of Japan p. 3492 - 3494 (1981)
Update date:2022-08-04
Topics:
Umehara, Takashi
Inouye, Yoshinobu
Kakisawa, Hiroshi
The irradiation of 5,5-dimethyl-3-(4-methyl-3-pentenyloxy)-2-cyclohexenone gave regioselectively, 6,6,10,10-tetramethyl-2-oxatricyclo<5.4.0.01,5>undecan-8-one, while, that of 5,5-dimethyl-3-<(3-methylcyclohexenyl)methoxy>-2-cyclohexenone afforded, regio- and stereoselectively, 1,5,5-trimethyl-8-oxatetracyclo<8.3.1.02,7.01,5>tetradecan-3-one.
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