807376-14-3

Upstream product

• 2978-30-5 2,2-dimethylpent-4-enenitrile 
• 123-11-5 4-methoxy-benzaldehyde 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 5497-67-6 2,2-dimethyl-4-pentenal 

Downstream Products

• 807376-03-0 ethyl 3-(4-methoxyphenyl)-4,4-dimethyl-3-vinylhept-6-enoate 
• 807376-82-5 ethyl 2-[1-(4-methoxyphenyl)-2,2-dimethylcyclopentyl]acetate 
• 807376-71-2 ethyl 2-[1-(4-methoxyphenyl)-5,5-dimethylcyclopent-3-en-1-yl]acetate 
• 807376-94-9 2-[1-(4-methoxyphenyl)-2,2-dimethylcyclopentyl]ethanol 
• 807375-34-4 (+/-)-infuscol A 
• 807375-34-4 (+/-)-infuscol B 
• 807375-34-4 neocuprenenol 
• 807375-34-4 (+/-)-cuprenenol 
• 807377-06-6 [1-(4-methoxy-phenyl)-2,2-dimethyl-cyclopentyl]-acetaldehyde 
• 852058-92-5 1-methoxy-4-(1,2,2-trimethyl-cyclopentyl)-cyclohexa-1,4-diene 
• 807376-38-1 3-(4-methoxyphenyl)-4,4-dimethylhepta-2,6-dien-1-ol 
• 807376-49-4 3-(4-methoxyphenyl)-4,4-dimethylhepta-1,6-dien-3-ol 
• 807377-98-6 4-(1,2,2-trimethylcyclopentyl)cyclohex-3-enone 
• 807376-60-9 3-(4-methoxyphenyl)-4,4-dimethylhepta-2,6-dienal 

Relevant academic research and scientific papers

Forming tertiary organolithiums and organocuprates from nitrile precursors and their bimolecular reactions with carbon electrophiles to form quaternary carbon stereocenters

Unstabilized tertiary organolithium intermediates are conveniently generated by reductive decyanation of nitriles, and these reagents and their derived cuprates couple in useful yields with carbon- centered electrophiles (see example). Chiral tertiary org

Total synthesis of (±)-infuscol A and (±)-cuprenenol

Total synthesis of the nonaromatic cuparenoid sesquiterpenes (±)-infuscol A and cuprenenol, and (±)-infuscol B and neocuprenenol isolated from the Japanese liverwort Jungermannia infusca has been accomplished. Two ring-closing metathesis reaction based st