80787-63-9

Usage

Uses

Unfortunately, the provided materials do not give any information about the uses of (4aS)-1,4a,5,6,11,11b-Hexahydro-11bβ-methyl-N-isopropyl-2H-benzo[a]carbazol-5α-amine. Further research would be needed to determine its potential applications in various industries.

Upstream product

• 57103-59-0 (+)-Aristoteline 
• 123843-27-6 (+/-)-anti-aristotelin-15-ol 
• 129011-41-2 (+/-)-aristomakinine 
• 67-64-1 acetone 

Relevant academic research and scientific papers

ARISTOMAKINE, A NOVEL INDOLE ALKALOID FROM ARISTOTELIA SERRATA

The isolation and structural determination of aristomakine (I), an unusual indole alkaloid with an N-isopropyl group, is reported.

Synthesis of Aristotelia-Type Alkaloids

Biomimetic syntheses of racemic aristomakinine ((+/-)-3) and aristomakine ((+/-)-4), an unusual indole alkaloid bearing an N-isopropyl group, are described.The key step is a Grob-type fragmentation of anti-15-aristotelinyl methanesulfonate ((+/-)-2) to the intermediate iminium ion I which, upon subsequent hydrolysis, furnished aristomakinine ((+/-)-3).On the other hand, the same intermediate could be reduced in situ to aristomakine ((+/-)-4).The controversial relative configurations of the two alkaloids have been firmly established by means of NOE difference experiments.