808113-99-7Relevant academic research and scientific papers
Total Synthesis of the Natural Carbazoles O -Demethylmurrayanine and Murrastanine A, and of a C4,C4′ Symmetric Murrastanine A Dimer from N -Phenyl-4,5-dimethylene-1,3-oxazolidin-2-one
Avila-Melo, José Luis,Benavides, Adriana,Fuentes-Gutiérrez, Alfredo,Tamariz, Joaquín,Jiménez-Vázquez, Hugo A.
, p. 2201 - 2211 (2021/03/15)
The synthesis of natural carbazoles O -demethylmurrayanine and murrastanine A starting from the title exo -heterocyclic diene- is described. In the synthesis of murrastanine A, its symmetric C4,C4′ dimer can be obtained as the sole product under rather mi
Total synthesis of the natural carbazoles Murrayanine and Murrayafoline A, based on the regioselective Diels-Alder addition of exo-2-oxazolidinone dienes
Benavides, Adriana,Peralta, Javier,Delgado, Francisco,Tamariz, Joaquin
, p. 2499 - 2504 (2007/10/03)
A new synthesis of the natural carbazoles Murrayanine (1) and Murrayafoline A (3) is described. The key step in the synthetic route involved the regioselective cycloaddition of the diene 4,5-dimethylene-3-phenyl-1,3- oxazolidin-2-one (4) to acrolein (6) c
