808142-70-3Relevant academic research and scientific papers
Expanding the scope of the Cu assisted Suzuki-Miyaura reaction
Crowley, Brendan M.,Potteiger, Craig M.,Deng, James Z.,Prier, Christopher K.,Paone, Daniel V.,Burgey, Christopher S.
, p. 5055 - 5059 (2011)
Recent advances in the development of the copper facilitated Suzuki-Miyaura reaction are described. Improvements include expansion of substrate scope to include aryl chlorides and polyhalo aryl boronates. It was found that use of S-Phos and X-Phos could a
Copper-facilitated Suzuki reactions: Application to 2-heterocyclic boronates
Deng, James Z.,Paone, Daniel V.,Ginnetti, Anthony T.,Kurihara, Hideki,Dreher, Spencer D.,Weissman, Steven A.,Stauffer, Shaun R.,Burgey, Christopher S.
supporting information; experimental part, p. 345 - 347 (2009/07/11)
(Chemical Equation Presented) The palladium-catalyzed Suzuki-Miyaura reaction has been utilized as one of the most powerful methods for C-C bond formation. However, Suzuki reactions of electron-deficient 2-heterocyclic coronates generally give low convers
Accelerated luminophore discovery through combinatorial synthesis
Lowry, Michael S.,Hudson, William R.,Pascal Jr., Robert A.,Bernhard, Stefan
, p. 14129 - 14135 (2007/10/03)
A method for accelerating the discovery of ionic luminophores using combinatorial techniques is reported. The photophysical properties of the resulting transition-metal-based chromophores were compared against a series of analogous, traditionally prepared species. The strong overlap between these two sets confirms the identity of the parallel synthesis products and supports the truthfulness of the combinatorial results. Further support for the combinatorial method comes from the adherence of these complexes to the energy gap law. The relationship between the structure of a complex and its photophysical properties was also considered, and static DFT calculations were used to assess whether it is feasible to predict the luminescent behavior of novel materials.
