80818-48-0

Upstream product

• 85738-15-4 N-benzyl-trans-8-azabicyclo<4.3.0>non-4-en-7-one 
• 4383-22-6 Allylbenzylamine 
• 66050-03-1 cis-2-benzyl-1,3,3a,4,7,7a-hexahydro-1,3-isoindoledione 
• 85738-15-4 N-benzyl-cis-8-azabicyclo<4.3.0>non-4-en-7-one 
• 80818-40-2 cis-N-benzyl-9-hydroxy-8-azabicyclo<4.3.0>nonan-7-one 
• 80818-42-4 N-benzyl-8-azabicyclo<4.3.0>nona-1(6),3-dien-7-one 
• 66050-00-8 2-benzylhexahydro-1H-isoindole-1,3(2H)-dione 
• 85738-10-9 N-allyl-N-benzylpenta-2(E),4-dienamide 
• 52126-35-9 trans 2,4-pentadienoyl chloride 
• 80818-41-3 N-benzyl-8-azabicyclo<4.3.0>non-1(6)-en-7-one 
• 80818-46-8 N-benzyl-trans-8-azabicyclo<4.3.0>non-3-en-7-one 

Relevant academic research and scientific papers

The Synthesis of 9-Substituted N-Benzyl-8-azabicyclonon-4-en-7-ones by the Intramolecular Diels-Alder Reaction

The intramolecular thermal cyclisation of N-allyl-N-benzylpenta-2(E),4-dienamide in refluxing NN-dimethylformamide gives N-benzyl-cis- and trans-8-azabicyclonon-4-en-7-one; N-allyl-N-benzylhexa-2(E),4(E)-dienamide gives (1RS, 3RS, 6SR)-3-methyl- an

Selective Reduction of αβ-Olefinic Amides and Lactams by Magnesium and Methanol

αβ-Olefinic amides with various substitution patterns at the carbon-carbon double bond and at nitrogen are all reduced to the corresponding saturated amides by magnesium and methanol.The same reducing system reduces N-benzyl-8-azabicyclonona-1(6),3-dien-7-ones at the conjugated double bond to give mixtures of the cis- and trans-dihydro-derivatives; the isolated, non-conjugated double bond is not reduced, even in the 3,4-diphenylsubstituted compound.Magnesium and methanol reduces quinolin-2(1H)-ones to their 3,4-dihydro-derivatives, and 5,6,7,8-tetrahydroquinolin-2(1H)-one to a mixture of two dihydro-derivatives.