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(C6H5)3P*Ni*(C6H5NCNC6H5)=((C6H5)3P)Ni(C6H5NCNC6H5) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

80834-11-3

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80834-11-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 80834-11-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 8,0,8,3 and 4 respectively; the second part has 2 digits, 1 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 80834-11:
(7*8)+(6*0)+(5*8)+(4*3)+(3*4)+(2*1)+(1*1)=123
123 % 10 = 3
So 80834-11-3 is a valid CAS Registry Number.

80834-11-3Relevant academic research and scientific papers

EINE CARBEN-METALLBINDUNG IN -NICKELABICYCLEN

Hoberg, Heinz,Burkhart, Georg,Krueger, C.,Tsay, Y. -H

, p. 343 - 352 (1981)

The complex (Ph3P)Ni(PhNCNPh) (II) is formed from (Ph3P)2Ni(PhNCNPh) (I) in toluene at 60 deg C.II can also be prepared directly from (COD)2Ni, Ph3P and PhNCNPh (45percent yield). (COD)2Ni reacts with diarylcarbodiimides in THF to give (ArNCNAr)3Ni(THF) (VIII).The structure of VIIIa (Ar = phenyl) has been determined by X-ray crystallography.The molecule is shown to contain a nickela bicyclic group in which the carbodiimide molecules are linked to form a 2,5,8-h3-carbene ligand.Some properties and reactions of II and VIII are described.

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