80842-46-2Relevant academic research and scientific papers
Some Chemical Transformations of 7a-Cyanohexahydro-1H-pyrrolizine into 7a-Substituted Hexahydro-1H-pyrrolizines
Miyano, Seiji,Yamashita, Osamu,Sumoto, Kunihiro,Shima, Keiyu,Hayashimatsu, Mariko,Satoh, Fumio
, p. 47 - 49 (2007/10/02)
Chemical transformations of 7a-cyanohexahydro-1H-pyrrolizine (2) into 7a-substituted hexahydro-1H-pyrrolizines are described.In the reaction of 2 with lithium aluminium hydride, the orientation of the lone pair of the bridgehead nitrogen against C-CN bond can be regarded as significant.
