808761-99-1Relevant articles and documents
Thieme chemistry journal awardees - where are they now? synthesis of the marine glycolipid dioctadecanoyl discoside
Florence, Gordon J.,Aslam, Tashfeen,Miller, Gavin J.,Milne, Gavin D. S.,Conway, Stuart J.
scheme or table, p. 3099 - 3102 (2010/03/02)
The first synthesis of the inositol-containing marine glycolipid dioctadecanoyl discoside is reported. The key glycosylation reaction proceeds with β-selectivity at reduced temperature. The separable anomers could be readily progressed to afford discoside
Direct chemical synthesis of the β-mannans: Linear and block syntheses of the alternating β-(1→3)-β-(1→4)-mannan common to Rhodotorula glutinis, Rhodotorula mucilaginosa, and Leptospira biflexa
Crich, David,Li, Wenju,Li, Hongmei
, p. 15081 - 15086 (2007/10/03)
Two stereocontrolled syntheses of a methyl glycoside of an alternating β-(1→4)-β-(1→3)-mannohexaose, representative of the mannan from Rhodotorula glutinis, Rhodotorula mucilaginosa, and Leptospira biflexa, are described. Both syntheses employ a combinati