80907-49-9Relevant academic research and scientific papers
Synthesis and reaction studies of phthaloylcobalt cations. Application to naphthoqulnone synthesis
Baysdon, Sherrol L.,Liebeskind, Lanny S.
, p. 771 - 775 (2008/10/08)
Cationic phthaloylcabalt complesee 3-7 havt bwn pwpard by reaction of dtiorcobdh phtholoyl complex 1 with AgBF4 ffJlowwl by irauant with the appropriate ligimd. RtncUon of Lae cutionic cnraplwa wilh dkyns produced luphthoqulnuse, diid lh mecbanittic nature af ths results is diacuiwd. The cafionic cobalt complex 6 with a chelatmg diphoa bgand wai found to rapidly give high yields of nub Ututad naphthoquinonea on treatment with fuiicuonaliied alkynao in CH2Cl2.
