809276-30-0

Basic information

• Product Name: N-{(3R,4S)-3-[1-(2-Hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-5-methoxymethoxy-4-methyl-pentanoyl}-benzamide
• Synonyms: N-{(3R,4S)-3-[1-(2-Hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-5-methoxymethoxy-4-methyl-pentanoyl}-benzamide
• CAS NO: 809276-30-0
• Molecular Weight: 414.458
• Mol File: 809276-30-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-{(3R,4S)-3-[1-(2-Hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-5-methoxymethoxy-4-methyl-pentanoyl}-benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-{(3R,4S)-3-[1-(2-Hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-5-methoxymethoxy-4-methyl-pentanoyl}-benzamide(809276-30-0)
• EPA Substance Registry System: N-{(3R,4S)-3-[1-(2-Hydroxy-phenyl)-meth-(E)-ylideneaminooxy]-5-methoxymethoxy-4-methyl-pentanoyl}-benzamide(809276-30-0)

Safety Data

• Hazardous Substances Data: 809276-30-0(Hazardous Substances Data)

Upstream product

• 21013-96-7 (E)-2-hydroxylbenzaldehyde oxime 
• 809276-00-4 N-((E)-(R)-5-Methoxymethoxy-4-methyl-pent-2-enoyl)-benzamide 
• 105164-22-5 (S)-3-methoxymethoxy-2-methylpropanal 

Relevant articles and documents

Enantioselective formal hydration of α,β-unsaturated imides by Al-catalyzed conjugate addition of oxime nucleophiles

The (salen)Al-catalyzed asymmetric conjugate addition of salicylaldoxime to α,β-unsaturated imides is the key step in an efficient and highly enantioselective two-step formal hydration of these electron-deficient olefins. This reaction constitutes the first example of an enantioselective conjugate addition of an oxygen-centered nucleophile to α,β-unsaturated carboxylic acid derivatives. Application of this method to chiral, nonracemic substrates revealed a high level of catalyst-induced diastereoselectivity, underscoring its potential utility for polyketide natural product synthesis. Copyright