80986-41-0Relevant academic research and scientific papers
Silver compounds in synthetic chemistry. Part 2: A convenient synthesis of 2,3,4,5,6-pentafluorophenones, C6F5COR, from pentafluorophenylsilver, AgC6F5, and the corresponding acid chlorides, RCOCl
Kremlev, Mikhail M.,Tyrra, Wieland,Naumann, Dieter,Yagupolskii, Yurii L.
, p. 1327 - 1331 (2005)
2,3,4,5,6-Pentafluorophenones are formed selectively from the reactions of pentafluorophenylsilver and carboxylic acid chlorides in moderate to excellent yields.
Decarboxylative Cross-Coupling of Acyl Fluorides with Potassium Perfluorobenzoates
Fu, Liyan,Chen, Qiang,Nishihara, Yasushi
supporting information, p. 6388 - 6393 (2020/08/24)
We report the transition metal-free decarboxylative cross-coupling reactions of acyl fluorides with potassium perfluorobenzoates. Compared with traditional transition metal-catalyzed cross-couplings, this protocol presents an extremely environmentally ben
REACTION OF ORGANOMETALLIC COMPOUNDS CATALYZED BY TRANSITION METAL COMPLEXES. III. THE ACYLDEMETALLATION OF ORGANOTIN COMPOUNDS CATALYZED BY BIS(?-ALLYLPALLADIUM CHLORIDE)
Bumagin, N. A.,Bumagina, I. G.,Kashin, A. N.,Beletskaya, I. P.
, p. 977 - 981 (2007/10/02)
A study was carried out on the reaction of organotin compounds RSnMe3 with carboxylic acid chlorides R'COCl (R'=Me, PhCH2, PhCH=CH, Ph, o-FC6H4, p-ClCOC6H4, p-NO2C6H4) catalyzed by bis(?-allylpalladium chloride) in hexametapol and acetone.The reaction proceeds at room temperature and gives high yields of asymmetrical ketones RCOR'.The stoichiometry of the reaction of PhCOPdCl(PPh3)2 with PhSnMe3 was studied.A possible mechanism for the catalytic acyldemetallation reaction was discussed.
