81056-91-9Relevant academic research and scientific papers
A NEW SYNTHESIS OF β-NITRO CARBONYL COMPOUNDS FROM ALKYL VINYL KETONES WITH SODIUM NITRITE-ACETIC ACID IN TETRAHYDROFURAN
Miyakoshi, Tetuo,Saito, Shojiro,Kumanotani, Ju
, p. 1677 - 1678 (1981)
The reaction of alkyl vinyl ketones with sodium nitrite-acetic acid in THF gave the corresponding β-nitro carbonyl compounds in 42-82percent yield.
"Head-to-head" dimerization and dehydrodimerization of vinyl ketones catalyzed by modified rhodium(I) complexes
Kovalev, I. P.,Kolmogorov, Yu. N.,Strelenko, Yu. A.,Ignatenko, A. V.,Vinogradov, M. G.,Nikishin, G. I.
, p. 125 - 133 (2007/10/02)
The dimerization of vinyl ketones RC(O)CH=CH2, I (R = Me, tBu, Ph, p-MeC6H4, cyclopropyl, 2-(5-methylfuryl)) at 80 deg C in the presence of the catalytic system 2-MCl2 leads preferably to either α,β-unsaturated 1,6-diketones RC(O)C
