810687-41-3Relevant academic research and scientific papers
Mechanism of 4,6-O-benzylidene-directed β-mannosylation as determined by α-deuterium kinetic isotope effects
Crich, David,Chandrasekera, N. Susantha
, p. 5386 - 5389 (2004)
Considerable oxacarbenium ion character may be in the transition state of a highly β-selective mannosylation reaction that proceeds via an α-mannosyl triflate. An α-deuterium kinetic isotope effect of 1.2 was measured at -78 °C (=1.1 at 25 °C). This infor
