81077-20-5Relevant academic research and scientific papers
A NEW CONVENIENT SYNTHESIS OF TRISUBSTITUTED 1,3-DIOXOLE-4-CARBOXYLATES FROM METHYL 2-DIAZO-3-OXOBUTYRATE AND ALDEHYDES
Alonso, Miguel E.,Chitty, A. Wladimir
, p. 4181 - 4184 (1981)
The interaction between methyl 2-diazo-3-oxobutyrate and the carbonyl group of aliphatic, aromatic, and α,β-unsaturated aldehydes under bis(hexafluoroacetoacetonato)copper(II) catalysis furnishes 1,3-dioxole-4-carboxylates in preparatively useful yields.T
Divergence of carbonyl ylide reactions as a function of diazocarbonyl compound and aldehyde substituent: Dioxolanes, dioxolenes, and epoxides
Russell, Albert E.,Brekan, Jonathan,Gronenberg, Luisa,Doyle, Michael P.
, p. 5269 - 5274 (2004)
The products from dirhodium(II) acetate-catalyzed reactions between diazocarbonyl compounds and a series of benzaldehydes demonstrate the extent of competition between intramolecular and intermolecular trapping of carbonyl ylide intermediates and the elec
