81090-88-2

Upstream product

• 81090-87-1 1,4,2',6'-tetrakis-N-(benzyloxycarbonyl)-3-O-demethylsporaricin B 
• 83866-00-6 1,2',6'-tris(N-benzyloxycarbonyl)-4-N,5-O-carbonyl-3-de(methoxy)-3-oxo-sporaricin B 
• 81090-88-2 1,2',6'-tris(N-benzyloxycarbonyl)-4-N,5-O-carbonyl-3-de(O-methyl)sporaricin B 
• 501-53-1 benzyl chloroformate 
• 75106-35-3 3-O-demethylsporaricin B 

Downstream Products

• 84247-53-0 3-O-allyl-1,2',6'-tris-N-(benzyloxycarbonyl)-4-N,5-O-carbonyl-3-O-demethylsporaricin B 
• 84247-60-9 3-O-(3-amino-2-hydoxypropyl)-3-O-demethylsporaricin A 
• 84247-61-0 3-O-demethyl-3-O-(2,3-dihydroxypropyl)sporaricin A 
• 84247-62-1 3-O-(4-amino-2-hydroxybutyl)-3-O-demethylsporaricin A 
• 86132-47-0 [(2R,3R,6S)-2-((1R,2R,3S,4S,6R)-4-Allyloxy-6-benzyloxycarbonylamino-2-hydroxy-3-methylamino-cyclohexyloxy)-6-((S)-1-benzyloxycarbonylamino-ethyl)-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester 
• 84247-55-2 3-O-allyl-1,2',6',2'''-tetrakis-N-(benzyloxycarbonyl)-3-O-demethylsporaricin A 
• 84247-56-3 1,2',6',2'''-tetrakis-N-(benzyloxycarbonyl)-3-O-demethyl-3-O-(2,3-epoxypropyl)-sporaricin A 
• 84247-59-6 1,2',6',2'''-tetrakis-N-(benzyloxycarbonyl)-3-O-demethyl-3-O-(2,3-dihydroxypropyl)sporaricin A 
• 84247-58-5 1,2',6',2'''-tetrakis-N-(benzyloxycarbonyl)-3-O-(3-cyano-2-hydroxypropyl)-3-O-demethylsporaricin A 
• 83865-97-8 1,2',6'-tris(N-benzyloxycarbonyl)-4-N,5-O-carbonyl-3-fluoro-3-de(methoxy)sporaricin B 
• 83865-98-9 [(2R,3R,6S)-6-((R)-1-Benzyloxycarbonylamino-ethyl)-2-((1R,2R,3S,4S,6R)-6-benzyloxycarbonylamino-4-fluoro-2-hydroxy-3-methylamino-cyclohexyloxy)-tetrahydro-pyran-3-yl]-carbamic acid benzyl ester 
• 83865-99-0 1,2',6'-tris(N-benzyloxycarbonyl)-4-N-(N-benzyloxycarbonylglycyl)-3-fluoro-3-de(methoxy)sporaricin B 
• 87039-07-4 3-fluoro-3-de(methoxy)sporaricin A hydrochloride 
• 83866-00-6 1,2',6'-tris(N-benzyloxycarbonyl)-4-N,5-O-carbonyl-3-de(methoxy)-3-oxo-sporaricin B 

Relevant academic research and scientific papers

SYNTHESES OF 3-FLUORO-, 3-EPI-3-FLUORO-, AND 3,3-DIFLUORO-3-DE(METHOXY)SPORARICIN A

3-Fluoro- (4), 3-epi-3-fluoro- (3), and 3,3-difluoro-3-de(methoxy)sporaricin A (5) have been prepared by reaction of diethylaminosulfur trifluoride with the corresponding precursors: 1,2',6'-tris(N-benzyloxycarbonyl)-4-N,5-O-carbonyl-3-de(O-methyl)sporari

SYNTHESES OF 3-O-SUBSTITUTED 3-O-DEMETHYLSPORARICINS A

The 3-O-methyl group of sporaricin A has been replaced by other alkyl groups to give 3-O-(3-amino-2-hydroxypropyl)- (13), 3-O-(4-amino-2-hydroxybutyl)- (15), and 3-O-(2,3-dihydroxypropyl)-sporaricin A (14).The 3-O-methyl group of sporaricin B was selectiv