81095-84-3

Upstream product

• 100-39-0 benzyl bromide 
• 81095-90-1 α-(hydroxyimino)-β-(N-methylindol-3-yl)-N-methylpropanamide 
• 603-76-9 1-methylindole 
• 392-12-1 Indole-3-pyruvic acid 
• 2687-43-6 O-benzylhydoxylamine hydrochloride 
• 81095-79-6 ethyl α-(benzyloximino)-β-(indol-3-yl)propanoate 
• 81095-80-9 α-(benzyloximino)-β-(N-methylindol-3-yl) propanoic acid 
• 81095-89-8 ethyl α-(hydroxyimino)-β-(N-methylindol-3-yl)propanoate 

Downstream Products

• 111192-61-1 1-(benzyloxamino)-2-(N-methylindolin-3-yl)-N-methylpropanamide 
• 111192-60-0 1-(benzyloximino)-2-(N-methylindol-3-yl)-2-oxo-N-methylropanamide 

Relevant academic research and scientific papers

A BIOMIMETIC APPROACH TO SPORIDESMINS. SYNTHESIS OF AN α,β-EPOXYTRYPTOPHAN DERIVATIVE

The reaction of 19 - prepared efficiently from 16 - with DDQ affords 22.This epoxide may serve as a model compound to investigate the biosynthesis of sporidesmins, e.g. 1 and 2.

N-Hydroxytryptophan in the Synthesis of Natural Products Containing Oxidized Dioxopiperazines. An Approach to the Neoechinulin and Sporidesmin Series

N-Hydroxytryptophan derivatives have been synthesized via two routes.In one procedure, the indole-3-pyruvate oximes 14b,c were reduced with trimethylamine-borane in the presence of ethanolic HCl to give 18 (Scheme III); aminolysis of the latter afforded 1