81113-84-0

Upstream product

• 100-58-3 phenylmagnesium bromide 
• 23974-72-3 sodium phenylselenide 
• 107037-20-7 2-(phenylselanyl)benzonitrile 
• 88048-84-4 2-formylphenyl phenyl selenide 
• 25562-42-9 2-(phenylselanyl)benzoic acid 

Downstream Products

• 113560-92-2 2-phenylselanyl-benzoic acid amide 
• 81389-54-0 2-(phenylseleno)benzoic anhydride 
• 81113-82-8 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one 
• 81113-83-9 1,1-dihydro-1-tert-butoxy-1-phenyl-3H-2,1-benzoxaselenol-3-one-1-oxide 
• 81113-85-1 2-carboxyphenyl phenyl selenoxide 
• 81389-55-1 2-carboxyphenyl phenyl selenone 
• 355409-87-9 ethyl o-(phenylseleno)benzoate 
• 80014-45-5 (Z)-methyl 2-(phenylseleno)benzoate 

Relevant academic research and scientific papers

A BODIPY fluorescence probe modulated by selenoxide spirocyclization reaction for peroxynitrite detection and imaging in living cells

We present the synthesis, spectroscopic properties, and live-cell application of a new BODIPY (boron dipyrromethene) fluorescence probe BOD-Se based on selenoxide spirocyclization reaction for peroxynitrite detection. The probe employs BODIPY dye as fluorophore, and is integrated with a chemical peroxynitrite responsive organoselenium functional group. By using reactive diaryl selenide and modulating by intramolecular charge-transfer (ICT) process, the probe is employed for evaluating intracellular peroxynitrite level changes. Different intracellular peroxynitrite levels can be detected with BOD-Se by confocal microscopy experiments using mouse macrophage cell line RAW264.7.

Syntheses and reactions of cyclic Se-alkoxy-Se-chloroselenuranes and alkoxyselenonium salts

Several 1-chloro-2,1-oxaselenole selenuranes 3a-e and selenonium salts 4a-c and 5-chloro-5,11-epoxy-6,11-dihydrodibenzo[b,e]selenepines 12a and 12b and selenonium salts 13a-c-were synthesized, and their reactions with organometallic reagents were studied.