81156-49-2Relevant academic research and scientific papers
UMPOLUNG OF REACTIVITY OF ALLYLSILANE, ALLYLGERMANE, AND ALLYLSTANNANE VIA THEIR REACTION WITH THALLIUM (III) SALT: A NEW ALLYLATION REACTION FOR AROMATIC COMPOUND
Ochiai, Masahito,Arimoto, Masao,Fujita, Eiichi
, p. 4491 - 4494 (1981)
A new direct allylation of the aromatic compound has been developed.A combination of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate gave rise to an allyl cationic species which was allowed to react with an aromatic compound, a nucleophile, to give allylation product(s) in good yields.
Pd(ii)-catalyzed decarboxylative allylation and Heck-coupling of arene carboxylates with allylic halides and esters
Wang, Jiantao,Cui, Zili,Zhang, Yuexia,Li, Huajie,Wu, Long-Min,Liu, Zhongquan
supporting information; experimental part, p. 663 - 666 (2011/03/22)
This work demonstrates an alternative method to prepare allylated arenes and aryl-substituted allylic esters via catalytic decarboxylative C-C bond formation using aromatic carboxylic acids and allylic halides and esters.
