UMPOLUNG OF REACTIVITY OF ALLYLSILANE, ALLYLGERMANE, AND ALLYLSTANNANE VIA THEIR REACTION WITH THALLIUM (III) SALT: A NEW ALLYLATION REACTION FOR AROMATIC COMPOUND

DOI: 10.1016/S0040-4039(01)93023-0

Source and publish data:

Tetrahedron Letters p. 4491 - 4494 (1981)

Update date:2022-08-04

Topics:

Authors:

Ochiai, Masahito

Arimoto, Masao

Fujita, Eiichi

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Article abstract of DOI:10.1016/S0040-4039(01)93023-0

A new direct allylation of the aromatic compound has been developed.A combination of allylsilane, allylgermane, or allylstannane and thallium (III) trifluoroacetate gave rise to an allyl cationic species which was allowed to react with an aromatic compound, a nucleophile, to give allylation product(s) in good yields.

Full text of DOI:10.1016/S0040-4039(01)93023-0

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