81171-44-0

Basic information

• Product Name: Silane, trimethyl[[1-(phenylmethoxy)ethenyl]oxy]-
• CAS NO: 81171-44-0
• Molecular Formula: C12H18O2Si
• Molecular Weight: 222.359
• Mol File: 81171-44-0.mol

Chemical Properties

• CAS DataBase Reference: Silane, trimethyl[[1-(phenylmethoxy)ethenyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trimethyl[[1-(phenylmethoxy)ethenyl]oxy]-(81171-44-0)
• EPA Substance Registry System: Silane, trimethyl[[1-(phenylmethoxy)ethenyl]oxy]-(81171-44-0)

Safety Data

• Hazardous Substances Data: 81171-44-0(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 5437-45-6 Benzyl bromoacetate 
• 140-11-4 Benzyl acetate 

Downstream Products

• 86000-10-4 benzyl 3-isopropylaminopropionate 
• 88517-47-9 3-Benzyloxyamino-butyric acid benzyl ester 
• 169215-94-5 (1,2,3-Triethoxy-4-oxo-cyclobut-2-enyl)-acetic acid benzyl ester 
• 180973-41-5 (E)-(R)-3-Hydroxy-7-tritylsulfanyl-hept-4-enoic acid benzyl ester 
• 180973-40-4 (E)-(S)-3-Hydroxy-7-tritylsulfanyl-hept-4-enoic acid benzyl ester 
• 188415-28-3 (S)-3-(3,4-Dimethoxy-phenyl)-3-hydroxy-propionic acid benzyl ester 

Relevant articles and documents

Platinum(II) complex-catalyzed enantioselective aldol reaction with ketene silyl acetals in DMF at room temperature

[{(R)-binap}Pt(μ-OH)]22X is a weak Lewis acid, which can catalyze the enantioselective aldol reaction of aldehydes with ketene silyl acetals in DMF at room temperature. The platinum(II) complex-catalyzed the enantioselective aldol reaction of a

ETUDE DE LA REACTION CHLOROCARBENE-ACETALS DE CETENES. I. SYNTHESE D'ESTERS α,β-ETHYLENIQUES.

The reaction of chloro, chloromethyl and chlorophenyl carbenoids with ketene alkylsilylacetals has been studied.Excellent yields of cyclopropanation were observed and the unstable chlorocyclopropanone acetals formed were thermally rearranged in high yield into α-substituted α,β-ethylenic esters.This new method for the synthesis of unsaturated esters appeared complementary of the known-ones.