81191-75-5Relevant academic research and scientific papers
Phosphorus Ylide Complexes of Platinum
Scherer, Otto J.,Jungmann, Heribert
, p. 1663 - 1665 (2007/10/02)
The interaction of cis/trans- (1) with Ph3P gives the ylide complex cis-Cl (2), which forms cis- (3) on heating in benzene.In CH2Cl2, Ph3P is added again quantitatively with formation of 2.Irradiation of 3 with a 500 W lamp yields cis-Cl2Pt(PPh3)2.The ylide complexes 4 and 5 were prepared by treatment of 3 with (Me2N)3P or Ph3As. 3 and Ph2P(CH2)2PPh2 form the chelate ylide complex 6. - Keywords: Phosphorus Ylide Complexes, Synthesis, NMR Spectra
