2,2,3,3,4,4,5,5,6,6,6-Undecafluor-hexansaeure-octylester, also known as 2,2,3,3,4,4,5,5,6,6,6-Undecafluorohexanoic acid octyl ester, is a complex organic compound with the chemical formula C14H11F11O2. It is a colorless liquid at room temperature and is characterized by its unique structure, which includes a hexanoic acid chain with eleven fluorine atoms and an octyl ester group. 2,2,3,3,4,4,5,5,6,6,6-Undecafluor-hexansaeure-octylester is primarily used in various industrial applications, such as in the production of specialty chemicals, lubricants, and as a component in certain types of fire-fighting foams. Due to its fluorinated nature, it possesses unique properties, such as resistance to heat and chemical reactions, which make it valuable in specific technical and industrial processes. However, it is important to handle 2,2,3,3,4,4,5,5,6,6,6-Undecafluor-hexansaeure-octylester with care due to its potential environmental and health impacts, and it is subject to regulatory controls to ensure safe use.
The CAS Registry Mumber 812-96-4 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 8,1 and 2 respectively; the second part has 2 digits, 9 and 6 respectively. Calculate Digit Verification of CAS Registry Number 812-96: (5*8)+(4*1)+(3*2)+(2*9)+(1*6)=74 74 % 10 = 4 So 812-96-4 is a valid CAS Registry Number.
The successful generation of perfluoroalkyl radicals (Rf˙) through photoredox catalysis has inspired us to investigate the preparation of various organofluorine species. In this work, visible light-induced photocatalytic reactions for the preparation of perfluoroalkyl amides and esters from the corresponding amines and alcohols using different types of triplet emitters as photocatalysts have been studied. The effects of the excited-state characteristics and redox potentials of the photocatalysts have been elucidated. Under optimized reaction conditions, these reactions can be performed successfully with different types of amines or alcohols and perfluoroalkyl iodides. Detailed mechanistic studies based on emission quenching experiments have been performed to study the photocatalytic cycles as well as the role of the different reagents. The proposed mechanism has also been examined by DFT calculations.
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