81267-86-9Relevant articles and documents
Chemistry of Trifluoromethyl-Sulfur-Nitrogen Compounds, XI. Reactions of (CFnCl3-nS)xNH3-x with Selected Aldehydes
Borowski, Herbert E.,Haas, Alois
, p. 523 - 532 (2007/10/02)
CF3SNH2 and CF2ClSNH2 react with formaldehyde to yield (RNCH2)n (n = 3, 4, 5, R = SCF3 2c, d, e; n = 3, 4, R = SCF2Cl 2a, b), (2f), (2g), (2h), and CF2ClSN(CH3)CH2N(CH3)SCF2Cl (3), respectively, and with benzaldehyde to give C6H5CH=NR (R = SCF3 1b, SCF2Cl 1a). (CF3S)2NH reacts with formaldehyde under various conditions to yield (CF3S)2NCH2OH (4), (CF3S)2NxCH2N(SCF3)2 (x = 0 - 5, 5a - f), (CF3S)2NmCH2N(SCF3)2 (m = 1, 2, 6a, b), and (CF3SNH2)3 (2c).In the reaction of the less reactive (CF2ClS)2NH with formaldehyde (CF3ClS)2NnCH2N(SCF2Cl)2 (n = 1, 2, 8a, b) are obtained.The base adduct (CF3S)2NH.N(CH3)3 decomposes thermally to yield (CF3S)2NCH2N(H)SCF3 (7) and 5a.A reaction path is proposed.IR-, 1H-, 13C-, 19F NMR data well as mass spectra are presented.