81292-97-9

Basic information

• Product Name: 4-Chlor-2-methyl-1-benzolsulfonsaeure-trimethylsilylester
• CAS NO: 81292-97-9
• Molecular Weight: 278.832
• Mol File: 81292-97-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Chlor-2-methyl-1-benzolsulfonsaeure-trimethylsilylester(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Chlor-2-methyl-1-benzolsulfonsaeure-trimethylsilylester(81292-97-9)
• EPA Substance Registry System: 4-Chlor-2-methyl-1-benzolsulfonsaeure-trimethylsilylester(81292-97-9)

Safety Data

• Hazardous Substances Data: 81292-97-9(Hazardous Substances Data)

Upstream product

• 4353-77-9 chlorosulfonate de trimethylsilyle 
• 108-41-8 1-chloro-3-methylbenzene 

Relevant articles and documents

Sulfosilylation of Aromatic Hydrocarbons by Trimethylsilyl Chlorosulfonate

Aromatic hydrocarbons 2 ,6 ,8 ,9 ,13 ,16 ,18 ,19 ,22 react with trimethylsilyl chlorosulfonate (1) to give trimethylsilyl arenesulfonates 5, 7, 11, 12, 15, 23 or sulfonic acids 17, 20, 21.If trimethylsilyl sulfonates are obtained, working up of the sulfonation mixtures is possible by distillation.By hydrohalogenolysis of trimethylsilyl sulfonates 5 at 0-5 deg C anhydrous sulfonic acids 3 result.The pathways to diphenylsulfone (25a) in the reaction of benzene (2a) with 1 were investigated.In this connection we succeeded in synthesizing benzenepyrosulfonic acid (28) and trimethylsilyl benzenepyrosulfonate (29).