81358-53-4

Basic information

• Product Name: 1-chloro-1-phenylthiobutan-3-one
• Synonyms: 1-chloro-1-phenylthiobutan-3-one
• CAS NO: 81358-53-4
• Molecular Weight: 214.716
• Mol File: 81358-53-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-chloro-1-phenylthiobutan-3-one(CAS DataBase Reference)
• NIST Chemistry Reference: 1-chloro-1-phenylthiobutan-3-one(81358-53-4)
• EPA Substance Registry System: 1-chloro-1-phenylthiobutan-3-one(81358-53-4)

Safety Data

• Hazardous Substances Data: 81358-53-4(Hazardous Substances Data)

Upstream product

• 108-98-5 thiophenol 
• 6110-01-6 4-phenylsulfanyl-butan-2-one 

Downstream Products

• 108644-07-1 (Z)-4-(phenylsulfonyl)but-3-en-2-one 
• 21860-46-8 (E)-β-acetylvinyl phenyl sulphone 
• 33944-97-7 (Z)-4-phenylsulfinyl-3-buten-2-one 
• 33944-98-8 (E)-(phenylsulfinyl)but-3-en-2-one 

Relevant articles and documents

The Preparation of Some β-Sulfonylacrylate Thioesters and β-Sulfonylvinyl Ketones

β-Sulfonylacrylate phenyl and t-butyl thioesters, and β-sulfonylvinyl ketones have been prepared by oxidation of the corresponding β-aryl- and β-alkyl-thio compounds.In one case the β-sulfonylvinyl ketone was obtained from an epoxy sulfone.The β-aryl- and β-alkyl-thio compounds were obtained by chlorination-dehydrochlorination of saturated precursors.The reactions of 3-(phenylthio)propionyl chloride with organocadmium and Grignard reagents were used to prepare some of the saturated precursors of the β-sulfonylvinyl ketones.