6110-01-6

Usage

Uses

Used in Pharmaceutical Industry:
4-PHENYLSULFANYL-BUTAN-2-ONE is used as a starting material for the synthesis of various pharmaceuticals due to its reactivity and ability to form a wide range of organic compounds with potential medicinal properties.
Used in Perfumery Industry:
In the perfumery industry, 4-PHENYLSULFANYL-BUTAN-2-ONE is utilized as a key component in the creation of fragrances, capitalizing on its distinctive fruity, sulfurous odor to contribute unique scents to perfume blends.
Used in Flavoring Industry:
4-PHENYLSULFANYL-BUTAN-2-ONE is employed as a flavoring agent, leveraging its characteristic odor to enhance the taste profiles of various food and beverage products.
Used in Specialty Chemicals Production:
4-PHENYLSULFANYL-BUTAN-2-ONE is used as an intermediate in the production of specialty chemicals, where its chemical properties allow for the development of unique and high-value products.
Used in Agricultural Applications:
4-PHENYLSULFANYL-BUTAN-2-ONE finds use in agriculture, potentially serving as a component in the formulation of agrochemicals or as a starting material for the synthesis of compounds with pesticidal or other agricultural benefits.
Used in Organic Materials Preparation:
Recognized for its potential as an intermediate, 4-PHENYLSULFANYL-BUTAN-2-ONE is also studied for its role in the preparation of organic materials, indicating its broad applicability in material science and related fields.

InChI:InChI=1/C10H12OS/c1-9(11)7-8-12-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3

Upstream product

• 78-94-4 methyl vinyl ketone 
• 108-98-5 thiophenol 
• 6322-49-2 4-chloro-2-butanone 
• 20524-74-7 Dibutylthioborsaeure-phenylester 
• 75-09-2 dichloromethane 
• 27998-52-3 (+/-)-4-(phenylthio)-2-butanol 
• 3588-30-5 2-methoxy-1,3-butadiene 
• 882-33-7 diphenyldisulfane 
• 100-68-5 methyl-phenyl-thioether 
• 69567-06-2 (N-methylanilino)prop-2-enenitrile 
• 74-88-4 methyl iodide 

Downstream Products

• 93766-71-3 5-Benzenesulfinyl-3-hydroxy-2,3-dimethyl-pentanoic acid methyl-phenyl-amide 
• 691890-02-5 (S)-2-hydroxy-2-methyl-4-phenylthiobutyronitrile 
• 691359-47-4 (S)-2-hydroxy-2-methyl-4-(phenylthio)butanoic acid 
• 1598407-29-4 4-hydroxy-3-mesityl-6-(2-(phenylthio)ethyl)-2H-pyran-2-one 
• 27998-52-3 (+/-)-4-(phenylthio)-2-butanol 
• 72863-20-8 α,α-Dimethylallyl phenyl sulfone 
• 15874-80-3 3-methyl-1-(phenylsulfonyl)but-2-ene 
• 72863-24-2 (E)-(but-2-en-1-ylsulfonyl)benzene 
• 54897-36-8 1-(but-3-en-2-ylsulfonyl)benzene 
• 129483-63-2 (Z)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-3-methyl-5-phenylsulfanyl-pent-2-enoic acid methyl ester 
• 129483-53-0 (Z)-2-[3-(tert-Butyl-dimethyl-silanyloxy)-propyl]-3-methyl-5-phenylsulfanyl-pent-2-enal 
• 129483-52-9 3-[1-Methyl-3-phenylsulfanyl-prop-(Z)-ylidene]-tetrahydro-pyran-2-one 
• 129840-88-6 2-(3-Benzenesulfinyl-1-hydroxy-1-methyl-propyl)-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid ethyl ester 
• 129840-92-2 C₁₈H₂₀O₃S 

Relevant academic research and scientific papers

Unusual sulfanylation through ring transformation of arene-tethered 2H-pyran-2-ones by in situ built Michael adduct

A novel synthesis of highly functionalized alkylsulfanylmethyl arenes 8a-m through the ring transformation of 6-aryl-4-methyl/ethylsulfanyl-2H-pyran-2-one-3-carbonitriles 1a-j, by reaction with methyl vinyl ketone 2, is delineated and illustrated. To asce

A mild and chemoselective CALB biocatalysed synthesis of sulfoxides exploiting the dual role of AcOEt as solvent and reagent

A mild, chemoselective and sustainable biocatalysed synthesis of sulfoxides has been developed exploiting CALB and using AcOEt with a dual role of more environmentally friendly reaction solvent and enzyme substrate. A series of sulfoxides, including the drug omeprazole, have been synthesised in high yields and with excellent E-factors.

Photo-Biocatalytic Cascades for the Synthesis of Volatile Sulfur Compounds and Chemical Building Blocks

Biocatalysis is a branch of catalysis that exploits enzymes to perform highly stereoselective chemical transformations under mild and sustainable conditions. This Synpact highlights how biocatalysis can be used in the synthesis of chiral 1,3-mercaptoalkan

Photo-biocatalytic One-Pot Cascades for the Enantioselective Synthesis of 1,3-Mercaptoalkanol Volatile Sulfur Compounds

The synthesis of enantiomerically pure 1,3-mercaptoalkanol volatile sulfur compounds through a one-pot photo-biocatalytic cascade reaction is described. Two new KRED biocatalysts with opposite enantioselectivity were discovered and proved to be efficient

Enantioselective Synthesis of Quaternary Δ4- and Δ5-Dehydroprolines Based on a Two-Step Formal [3+2] Cycloaddition of α-Aryl and α-Alkyl Isocyano(thio)acetates with Vinyl Ketones

A divergent synthesis of optically active quaternary Δ4- and Δ5-dehydro prolines is developed based on the first catalytic enantioselective conjugate addition of α-substituted isocyano(thio)acetates to vinyl ketones that is general for both α-aryl and α-alkyl isocyano(thio)acetates. The new tetrasubstituted C?N stereocenter is formed without the need of any metal salt due to a bifunctional tertiary amine/squaramide catalyst, featuring a bulky polyaryl sidearm and an unusually short squaramide diamide H???H interatomic distance in the solid state.

Functionalized α-oximinoketones as building blocks for the construction of imidazoline-based potential chiral auxiliaries

Functionalized α-oximinoketones with β-alkoxy, β-alkyl, and β-sulfenyl groups were used as efficient synthons for the preparation of chiral 1-acyl-4-imidazolin-2-ones and 1-acylimidazolidin-2-ones. For the preparation of the former heterocycles, α-oximinoketones were transformed into their respective imidazole N-oxides by neutral treatment with a chiral triazine, followed by reaction with acetic or propionic anhydrides to furnish the desired chiral 1-acetyl- or 1-propionyl-4-imidazolin-2-ones in moderate overall yields. Upon palladium hydroxide-catalyzed hydrogenation, these series were converted into their corresponding 1-acylimidazolidin-2-ones in high diastereoisomeric ratios. Thus, these novel chiral 1-acetyl- and 1-propionyl-imidazolidin-2-ones were obtained with a variety of alkyl groups at the C-4 and C-5 positions of the heterocycle, through a three-step methodology, and can be applied as new potential chiral auxiliaries.

N-heterocyclic carbene catalyzed carba-, sulfa-, and phospha-Michael additions with NHC·CO2 adducts as precatalysts

N-heterocyclic carbene catalyzed Michael additions have been revisited with 1,3-dialkyl- or 1,3-diarylimidazol(in)ium-2-carboxylates, that is, NHC·CO2 adducts, as the source of the free NHC catalysts in solution. Using these precatalysts, a number of efficient carba-, sulfa-, and phospha-Michael additions were achieved very conveniently, without the need for an external strong base to generate the NHC by deprotonation of an azolium salt. To further expand the scope of the procedure, some NHC-catalyzed sulfa-Michael/aldol organocascades were also investigated.

PYRONE COMPOUNDS AND HERBICIDES COMPRISING THE SAME

The present invention provides a compound having an excellent efficacy for controlling weeds. A pyrone compound of formula (I): wherein m is 1, 2 or 3; n is an integer of any one of 1 to 5; X represents O, S, S(O) or S(O)2; R1 repres

Selectivity reversal during thia-Michael additions using tetrabutylammonium hydroxide: Operationally simple and extremely high turnover

The use of tetrabutylammonium hydroxide as a novel and exceedingly efficient thia-Michael addition catalyst is herein described. This extremely simple methodology allows for the conjugate addition of a wide variety of mercaptan nucleophiles, and functions remarkably well with a very wide range of both classical and non-classical Michael acceptors. Contradistinctive to current literature reports, the use of this catalyst more efficiently promotes the addition of more basic thiols. This methodology is especially attractive and operationally simple, as it generally proceeds with only 1 mol% catalytic loading and without excess reagent, and the produced products typically require no purification. Georg Thieme Verlag Stuttgart New York.