81372-29-4Relevant academic research and scientific papers
Cathodic intra- and intermolecular couplings of ketones with unsaturated silanes
Kashimura, Shigenori,Ishifune, Manabu,Murai, Yoshihiro,Moriyoshi, Naotake,Shono, Tatsuya
, p. 5041 - 5044 (2007/10/02)
The electroreduction of 6-trimethylsilyl-6-hepten-2-one afforded cis-1- methyl-3-trimethylsilyl cyclohexanol, and γ-trimethylsilyl alcohols were yielded as the intermolecular coupling products when the cathodic reduction of ketones was carried out in the presence of unsaturated silanes.
A NEW REACTION IN ORGANOSILICON CHEMISTRY: THE OXIDATIVE FRAGMENTATION OF γ-HYDROXY SILANES
Wilson, Stephen R.,Zucker, Paul A.,Kim, Chong-wan,Villa, Carmine A.
, p. 1969 - 1972 (2007/10/02)
The Ce(4+) fragmentation of γ-hydroxy silanes leads to keto-olefins of predictable structure and stereochemistry.
lithium: A New Reagent for Carbonyl Reductive Vinylation
Wilson, Stephen R.,Shedrinsky, Alexander
, p. 1983 - 1984 (2007/10/02)
The direct transformation of a carbonyl compound into a vinyl compound (i.e., cyclohexanone vinylcyclohexane) is now possible with use of the new reagent described in this paper: lithium, followed by protodesilylation.
