81398-78-9Relevant academic research and scientific papers
Mechanism of the Facile Formation and Hydrolysis of Esters of o-Nitrobenzeneselenenic Acid: New Insight into the Mechanism of Nucleophilic Substitution Reactions of o-Nitrobenzeneselenenyl Derivatives
Kang, Sang-Ihn,Kice, John L.
, p. 295 - 301 (1986)
o-Nitrobenzeneselenenic acid (1) undergoes rapid acid-catalyzed esterification by alcohols to afford alkyl o-nitrobenzeneselenenates, o-O2NC6H4SeOR (2), in high yield.The mechanism of esterification of 1 and of its reverse, the hydrolysis of 2, has been i
Mechanism of the Reaction of Thiols with o-Nitro- and o-Benzoylbenzeneselenenic Acids and Anhydrides
Kice, John L.,McAfee, Farrell,Slebocka-Tilk, Henryka
, p. 3106 - 3114 (2007/10/02)
The kinetics of the reaction of an alkanethiol (n-BuSH) with o-nitro- (1a) and o-benzoylbenzeneselenenic (1b) acids (eq 3) and with the corresponding selenenic anhydrides (eq 4, 2a and 2b) have been investigated over a range of pH in a series of buffers i
THE ANHYDRIDE STRUCTURE OF SEVERAL PREVIOUSLY REPORTED STABLE ARSENESELENENIC ACIDS
Kice, John L.,McAfee, Farrell,Slebocka-Tilk, Henryka
, p. 3323 - 3326 (2007/10/02)
The compounds previously reported to be the stable areneselenenic acids, o-nitro- (1a) and o-benzoylbenzeneselenenic acid (1b), are shown actually to be the corresponding selenenic anhydrides (ArSeOSeAr).Solutions of the selenenic acids (ArSeOH), however,
