Mechanism of the Facile Formation and Hydrolysis of Esters of o-Nitrobenzeneselenenic Acid: New Insight into the Mechanism of Nucleophilic Substitution Reactions of o-Nitrobenzeneselenenyl Derivatives

DOI: 10.1021/jo00353a004

Source and publish data:

Journal of Organic Chemistry p. 295 - 301 (1986)

Update date:2022-08-04

Topics: Derivatives Hydrolysis Nucleophilic substitution Mechanism Esters

Authors:

Kang, Sang-Ihn

Kice, John L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00353a004

o-Nitrobenzeneselenenic acid (1) undergoes rapid acid-catalyzed esterification by alcohols to afford alkyl o-nitrobenzeneselenenates, o-O2NC6H4SeOR (2), in high yield.The mechanism of esterification of 1 and of its reverse, the hydrolysis of 2, has been i

Full text of DOI:10.1021/jo00353a004

Products guided by the article

Product name:C₁₀H₁₃NO₂SSe

Cas No:81398-78-9

R&D Labs maybe for 81398-78-9

VanderArk International Limited

Contact:86-10-82437576

Address:Qing He
shanghai payne pharm co.,ltd.

Contact:+86-021-58123769

Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
N&R INDUSTRIES,INC

Contact:Tel:+86-29-88764861 Fax:+86-29-88764861

Address:Rm#2107, Block A, Epin Meidao Building, Gaoxin Rd, Hi-Tech Zone, Xi’an, China
Chengda Pharmaceuticals Co., Ltd.

Contact:+86-573-84601188

Address:hengshan Road 5# in Jiashan, zhejiang
WD Silicone Co., Ltd

Contact:+86-27-87204219, +86-27-87215023

Address:2402, HuiGu Space-time Building, 8 Forest Road, East Lake Hi-Tech Development Zone

Relevant to this article

Regio- and enantioselective allylic substitution with less active N- or O-nucleophiles catalyzed by iridium-complex of bis(oxazolinyl)pyridine

Doi:10.1248/cpb.59.714
(2011)
Bulky amine analogues of ketoprofen: Potent antiinflammatory agents

Doi:10.1021/jm00378a027
(1984)
ENAMINE CHEMISTRY-XXIII. THE <4+2> CYCLOADDITION REACTIONS BETWEEN ENAMINOTHIONES AND ELECTROPHILIC OLEFINS AND ACETYLENES

Doi:10.1016/S0040-4020(01)98900-8
(1981)
Cr(III)(salen)Cl catalyzed enantioselective intramolecular addition of tertiary enamides to ketones: A general access to enantioenriched 1H-pyrrol-2(3H)-one derivatives bearing a hydroxylated quaternary carbon atom

Doi:10.1021/ja904534t
(2009)
On the way to biodegradable poly(hydroxy butyrate) from propylene oxide and carbon monoxide via β-butyrolactone: Multisite catalysis with newly designed chiral indole-imino chromium(III) complexes

Doi:10.1016/j.jorganchem.2009.04.013
(2009)
Asymmetric synthesis of 4H-1,3-oxazines: Enantioselective reductive cyclization of N-acylated β-amino enones with trichlorosilane catalyzed by chiral Lewis bases

Doi:10.1039/b905102c
(2009)

Article Doi