Mechanism of the Facile Formation and Hydrolysis of Esters of o-Nitrobenzeneselenenic Acid: New Insight into the Mechanism of Nucleophilic Substitution Reactions of o-Nitrobenzeneselenenyl Derivatives

DOI: 10.1021/jo00353a004

Source and publish data:

Journal of Organic Chemistry p. 295 - 301 (1986)

Update date:2022-08-04

Topics: Derivatives Hydrolysis Nucleophilic substitution Mechanism Esters

Authors:

Kang, Sang-Ihn

Kice, John L.

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Article abstract of DOI:10.1021/jo00353a004

o-Nitrobenzeneselenenic acid (1) undergoes rapid acid-catalyzed esterification by alcohols to afford alkyl o-nitrobenzeneselenenates, o-O2NC6H4SeOR (2), in high yield.The mechanism of esterification of 1 and of its reverse, the hydrolysis of 2, has been i

Full text of DOI:10.1021/jo00353a004

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