81452-72-4Relevant academic research and scientific papers
A study of epoxyolefin cyclizations catalyzed by bismuth trifluoromethanesulfonate and other metal triflates
Lacey, Joshua R.,Anzalone, Peter W.,Duncan, Christopher M.,Hackert, Matthew J.,Mohan, Ram S.
, p. 8507 - 8511 (2007/10/03)
Epoxyolefin cyclizations have attracted considerable interest due to their importance in biosynthetic pathways. Bismuth trifluoromethanesulfonate as well as several other metal triflates are shown to be highly effective (0.1 mol %) catalysts for the cycli
Glycinoeclepins, Natural Hatching Stimuli for the Soybean Cyst Nematode, Heterodera Glycines. II. Structural Elucidation
Masamune, Tadashi,Fukuzawa, Akio,Furusaki, Akio,Ikura, Mitsuhiko,Matsue, Hideki,et al.
, p. 1001 - 1014 (2007/10/02)
The structures of three new compounds, glycinoeclepsins A, B, and C, isolated from the hatch-stimulating extracts of kidney beans for the soybean cyst nematode, have been determined.The structures were resolved by using spectroscopic methods, especially b
Preparation of 2-exo-Hydroxy-7-oxabicyclo[2.2.1]heptanes
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, (2008/06/13)
2-exo-Hydroxy-7-oxabicyclo[2.2.1]heptanes are prepared by treating the corresponding cis-epoxycyclohexanol with acid in an inert solvent or by treating a 3-cyclohexen-1-ol which will produce the corresponding cis-epoxy alcohol successively or concurrently with an oxidizing agent and an acid in an inert solvent.
CYCLOHEXENOL ANNULATION VIA THE ALKOXY-ACCELERATED REARRANGEMENT OF VINYLCYCLOBUTANES
Danheiser, Rick L.,Martinez-Davila, Carlos,Sard, Howard
, p. 3943 - 3950 (2007/10/02)
The lithium and potassium salts of 2-vinylcyclobutanols undergo vinylcyclobutane rearrangement at 25-70 gradC, providing an efficient method for the synthesis of 3-cyclohexenol derivatives. 2-Vinylcyclobutanones are prepared from α,β-unsaturated carbonyl
