81455-00-7Relevant academic research and scientific papers
An efficient catalyst for ring opening of epoxides with phenol and thiophenol under solvent-free conditions
Lu, Hong-Fei,Zhou, Jun-Tao,Cheng, He-Long,Sun, Lei-Lei,Yang, Fei-Fei,Wu, Run-Ze,Gao, Yu-Hua,Luo, Zhi-Bin
, p. 11174 - 11184 (2013)
An efficient and rapid procedure for ring opening reaction of various epoxides with phenol and thiophenol derivatives was developed. The procedure can be obtained at room temperature under solvent-free condition in presence of (C4H12N2)2[BiCl6] Cl·H2O (1 mol %). This catalyst can be reused several times without significant loss of activity.
Enzymatic hydrolysis and esterification. Routes to optically pure cyclopentanols
Seemayer, R.,Schneider, M. P.
, p. 171 - 174 (2007/10/02)
Using an esterhydrolase from Pseudomonas sp. (SAM II), a series of optically pure cyclopentanols 1-4 was prepared by enzymatic hydrolysis of their corresponding acetates.Using the same enzyme, these cyclopentanols were esterified by enol esters as acyl do
