81500-90-5Relevant academic research and scientific papers
Structural and electronic studies of substituted: M -terphenyl lithium complexes
Valentine, Andrew J.,Geer, Ana M.,Taylor, Laurence J.,Teale, Andrew M.,Wood, Katherine E.,Williams, Huw E. L.,Lewis, William,Argent, Stephen P.,McMaster, Jonathan,Kays, Deborah L.
supporting information, p. 722 - 728 (2021/01/28)
The effect of para-substitution upon the structural and electronic properties of a series of m-terphenyl lithium complexes [R-Ar#-Li]2 (R = t-Bu 1, SiMe32, H 3, Cl 4, CF35; where R-Ar# = 2,6-{2,6-Xyl}2-4-R-C6H2 and 2,6-Xyl = 2,6-Me2C6H3) has been investig
Remote trimethylsilyl groups interfering with the ortho deprotonation of fluoroarenes and chloroarenes
Heiss, Christophe,Marzi, Elena,Mongin, Florence,Schlosser, Manfred
, p. 669 - 675 (2007/10/03)
(2-Fluorophenyl)trimethylsilane (2-F) and (2-chlorophenyl)-trimethylsilane (2-Cl) react with sec-butyllithium or lithium 2,2,6,6-tetramethylpiperidide under permutational hydrogen/metal interconversion (metalation) more slowly than, respectively, the corr
Peculiarities in the cleavage by methyllithium of unsymmetrical disilanes
Hevesi,Dehon
, p. 8031 - 8032 (2007/10/02)
The title reactions did not produce the more stable silyl anions from the disilanes studied, they either occurred by attack at the more electrophilic silicon atom, or led to unexpected products.
SILA-SUBSTITUTED PERFUMES. IV. SILA DERIVATIVES OF SOME MUSK SCENTS
Wrobel, Dieter,Wannagat, Ulrich
, p. 203 - 210 (2007/10/02)
The sila derivatives XII and XIII and the germa derivative XIV of the artificial musk scents 3,5-di(tert.butyl)benzaldehyde (A) and 3,5-di(tert.butyl)acetophenone (B) as well as the sila and germa derivatives XVIII and XIX of the "xylene musk" scent C, 2,
