81504-90-7

Basic information

• Product Name: methyl 8-benzyloxy-5-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate
• Synonyms: methyl 8-benzyloxy-5-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate
• CAS NO: 81504-90-7
• Molecular Weight: 340.376
• Mol File: 81504-90-7.mol

Chemical Properties

• CAS DataBase Reference: methyl 8-benzyloxy-5-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 8-benzyloxy-5-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate(81504-90-7)
• EPA Substance Registry System: methyl 8-benzyloxy-5-methoxy-1-oxo-1,2,3,4-tetrahydronaphthalene-2-carboxylate(81504-90-7)

Safety Data

• Hazardous Substances Data: 81504-90-7(Hazardous Substances Data)

Upstream product

• 81504-89-4 8-benzyloxy-5-methoxy-3,4-dihydronaphthalen-1(2H)-one 
• 616-38-6 carbonic acid dimethyl ester 
• 1015-55-0 5,8-dimethoxytetralone 
• 1203-34-5 8-hydroxy-5-methoxy-1,2,3,4-tetrahydro-1-naphthalenone 
• 100-39-0 benzyl bromide 

Downstream Products

• 81504-93-0 ethyl (-)-(2'S)-N-(8-benzyloxy-5-methoxy-3,4-dihydro-2-naphthoyl)prolinate 
• 81504-94-1 (-)-(2'S)-N-(8-benzyloxy-5-methoxy-3,4-dihydro-2-naphthoyl)proline 
• 81504-91-8 methyl 8-benzyloxy-5-methoxy-3,4-dihydronaphthalene-2-carboxylate 
• 81504-92-9 8-benzyloxy-5-methoxy-3,4-dihydronaphthalene-2-carboxylic acid 
• 93073-74-6 methyl 8-benzyloxy-1-hydroxy-5-methoxy-1,2,3,4-tetrahydronaphthalene-2-carboxylate 

Relevant articles and documents

Preparation of (-)-(7R)-7-Acetyl-7-hydroxy-4,4-dimethoxy-5,6,7,8-tetrahydronaphthalen-1(4H)-one, a Chiral AB-Synthon for Anthracycline Synthesis

The (-)-(R)-dienone (13) was prepared in 10 steps from the known 8-hydroxy-5-methoxy-2,3-dihydronaphthalen-1(4H)-one (2), and the chirality at C(7) in (13) corresponds to that found at C(9) in the naturally occurring anthracyclines related to daunomycin.