81524-37-0

Basic information

• Product Name: HRh(CO)(dppp)(dppp)monodentate
• CAS NO: 81524-37-0
• Molecular Weight: 956.826
• Mol File: 81524-37-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: HRh(CO)(dppp)(dppp)monodentate(CAS DataBase Reference)
• NIST Chemistry Reference: HRh(CO)(dppp)(dppp)monodentate(81524-37-0)
• EPA Substance Registry System: HRh(CO)(dppp)(dppp)monodentate(81524-37-0)

Safety Data

• Hazardous Substances Data: 81524-37-0(Hazardous Substances Data)

Upstream product

• 70196-25-7 {(C₆H₅)2P(CH₂)3P(C₆H₅)2}2RhH 
• 201230-82-2 carbon monoxide 
• 6737-42-4 1,3-bis-(diphenylphosphino)propane 
• 1333-74-0 hydrogen 

Relevant articles and documents

MONO- AND DINUCLEAR RHODIUM CARBONYL SPECIES CONTAINING MONODENTATE OR BRIDGING 1,3-BIS(DIPHENYLPHOSPHINO)PROPANE

The interaction of 2(μ-CO)2 with H2 in CH2Cl2 in the presence of varying amounts of dpp leads mainly to catalytically important species which include Rh(H)CO)(dpp)(dpp*) and 2(μ-dpp), these being formed also by treating RhH(dpp)2 with about 2 equivalents of CO; dpp and dpp* = bidentate and monodentate 1,3-bis(diphenylphosphino)propane, respectively.Mechanistic pathways involving a detected RhH(CO)2(dpp) and a non-detected RhH(CO)(dpp) species are suggested.