81556-13-0

Basic information

• Product Name: N'-(4-PHENYL-1,3-THIAZOL-2-YL)BENZENECARBOHYDRAZIDE
• Synonyms: N'-(4-PHENYL-1,3-THIAZOL-2-YL)BENZENECARBOHYDRAZIDE;TOSLAB 12891
• CAS NO: 81556-13-0
• Molecular Formula: C₁₆H₁₃N₃OS
• Molecular Weight: 295.36
• Mol File: 81556-13-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: N'-(4-PHENYL-1,3-THIAZOL-2-YL)BENZENECARBOHYDRAZIDE(CAS DataBase Reference)
• NIST Chemistry Reference: N'-(4-PHENYL-1,3-THIAZOL-2-YL)BENZENECARBOHYDRAZIDE(81556-13-0)
• EPA Substance Registry System: N'-(4-PHENYL-1,3-THIAZOL-2-YL)BENZENECARBOHYDRAZIDE(81556-13-0)

Safety Data

• Hazardous Substances Data: 81556-13-0(Hazardous Substances Data)

Upstream product

• 74087-90-4 2-Benzoylmethylthio-5-phenyl-1,3,4-oxadiazol 
• 3004-42-0 2-Mercapto-5-phenyl-1,3,4-oxadiazole 

Relevant articles and documents

Ring Transformation of 1,3,4-Oxadiazole to s-Triazole-Fused Heterocycles. New Synthetic Route for Thiazolo-s-triazole and 7H-s-Triazolothiadiazine

s-Triazole-fused heterocycles have been synthesized by an intramolecular transformation of some 1,3,4-oxadiazole ketones with ammonia or hydrazine.The α- ketone 2m gave thiazolo-s-triazole (4m), accompanied by a small amount of the hydrazide 9m on treatment with ammonium acetate in acetic acid.Similar treatment of ketones 2a and 2b afforded only the hydrazides 9a and 9b, respectively.Ketones 2a-n reacted with hydrazine hydrate in acetic acid to give 7H-s-triazolothiadiazines 5a-n.However, ketones 2o-q, with substituents α to the carbonyl group, could not be converted to the corresponding fused-ring systems.Mechanisms for these transformations are proposed.