815600-33-0

Upstream product

• 69739-34-0 t-butyldimethylsiyl triflate 
• 815600-30-7 (2R,3S,4R,5R,7R)-1-[(4R,5S)-5-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-7-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-8-methoxy-5-(4-methoxy-benzyloxy)-2,4-dimethyl-octan-1-one 
• 815600-27-2 (S)-4-Benzyl-3-[(2S,3R,5R)-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-6-methoxy-2-methyl-hexanoyl]-oxazolidin-2-one 
• 815600-29-4 (2S,3R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-3-(4-methoxy-benzyloxy)-2-methyl-hexanoic acid methoxy-methyl-amide 
• 815600-20-5 (2S,3R,5R)-5-(tert-Butyl-dimethyl-silanyloxy)-6-methoxy-3-(4-methoxy-benzyloxy)-2-methyl-hexanal 
• 819849-59-7 tert-butyl-[3-(4-methoxy-benzyloxy)-1-methoxymethyl-propoxy]-dimethyl-silane 
• 815600-28-3 (2S,3R,5R)-5-(t-butyldimethylsilyloxy)-3-hydroxy-N,6-dimethoxy-N,2-dimethylhexanamide 
• 815600-22-7 1-[(4S,5S)-5-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-propan-1-ol 
• 815600-19-2 1-[(4R,5S)-5-(2-Benzyloxy-ethyl)-2,2-dimethyl-[1,3]dioxolan-4-yl]-propan-1-one 
• 816458-94-3 {(4S,5S)-5-[2-(benzyloxy)ethyl]-2,2-dimethyl-1,3-dioxolan-4-yl}methanol 
• 276248-86-3 (R)-4-Methoxymethyl-2-(4-methoxy-phenyl)-[1,3]dioxane 
• 276248-87-4 (R)-1-Methoxy-4-(4-methoxy-benzyloxy)-butan-2-ol 
• 263543-10-8 (R)-3-(tert-butyldimethylsilyloxy)-4-methoxybutanal 
• 207123-20-4 (S,S)-2,2-dimethyl-4-(tert-butyldimethylsilyloxy)methyl-5-hydroxymethyl-1,3-dioxolane 

Relevant academic research and scientific papers

Synthetic studies on apoptolidin: Synthesis of the C12-C28 fragment via a highly stereoselective aldol reaction

The stereoselective and convergent synthesis of the C12-C28 segment 2 of the apoptosis inducing macrolide antibiotic, apoptolidin (1), is described. The synthesis involves a highly stereoselective tin(II)-mediated aldol reaction between the C17-C22 ethyl