81577-14-2

Upstream product

• 81577-09-5 3-(2,2,2-trifluoroethyl)chlorobenzene 

Downstream Products

• 81577-09-5 3-(2,2,2-trifluoroethyl)chlorobenzene 
• 128408-35-5 C₈H₅ClF₃⁽¹⁺⁾ 
• 100-14-1 4-nitrobenzyl chloride 
• 185140-83-4 1-(1-Chloro-2,2,2-trifluoro-1-methyl-ethyl)-3,5-difluoro-benzene 
• 619-23-8 3-Nitrobenzyl chloride 
• 75462-59-8 3,5-bis(trifluoromethyl)benzyl chloride 

Relevant academic research and scientific papers

MECHANISMS OF FREE-RADICAL REACTIONS. XIII. MECHANISM AND SELECTIVITY OF THE FREE-RADICAL HALOGENATION OF ALKYL AROMATIC HYDROCARBONS WITH FLUOROALKYL SUBSTITUENTS

The free-radical chlorination and bromination of 1-fluoro-2-arylethanes and 1,1,1-trifluoro-2-arylethanes was studied by the method of competing reactions.In all cases a good correalation between log krel and the Brown ?+ constants was observed.The variation of the selectivity in the transition from one reaction series to the other indicates that two independent factors which determine the reactivity (the change in the dissociation energy of the C-H bond and the polar effect of the substituents) have a simultaneous effect.