81581-29-5

Upstream product

• 56606-57-6 ethyl 2-bromo-3-(3,4-dimethoxyphenyl)-3-oxo-propanoate 
• 4687-37-0 ethyl 3,4-dimethoxybenzoylacetate 
• 76787-81-0 3-oxo-2-veratroyl-butyric acid ethyl ester 
• 944329-82-2 C₂₆H₂₈O₁₀ 
• 3535-37-3 3,4-dimethoxybenzoic acid chloride 
• 93-07-2 Veratric acid 
• 851-36-5 diethyl (3,4-dimethoxybenzoyl)malonate 

Downstream Products

• 4687-40-5 threo-diethyl 2,3-bis-(3,4-dimethoxybenzoyl)butane-1,4-dioate 
• 72536-39-1 threo-2,3-bis-(α-hydroxy-3,4-dimethoxybenzyl)butane-1,4-diol 

Relevant academic research and scientific papers

Simple synthesis of eudesmin through oxidative coupling of carbanions and reductive catalytic hydrogenation of diketo diester

A simple synthesis of eudesmin (1) is described. The key fragments were diol 13, dicarbethoxyethane 4, and diketo diester 5, which were prepared via reductive catalytic hydrogenation and oxidative intermolecular coupling of carbanions. This method is useful to generate the core skeleton of an endo-endo furofuran ring. Copyright Taylor & Francis Group, LLC.

Synthesis and N.m.r. Spectra of 2,6- and 2,4-Diaryl-3,7-dioxabicyclooctanes

A series of isomeric 2,6- and 2,4-diaryl-3,7-dioxabicyclooctanes have been prepared via the corresponding threo, and erythro-dioxo-diesters.Comparison of their 1H and 13C n.m.r. spectra reveals small differences in chemical shifts and coupling constants which could be diagnostic in assigning structures to such compounds.The structure of 4-hydroxysesamin has been confirmed by direct correlation with sesamin.