81583-86-0Relevant academic research and scientific papers
SELECTIVITY IN AN ASYMMETRIC NITROGEN INSERTION PROCESS
Aube, Jeffrey,Burgett, Paul M.,Wang, Yuguang
, p. 151 - 154 (2007/10/02)
A simple and efficient synthesis of chiral lactams utilizing a group-selective nitrogen insertion process has been investigated for a group of prochiral ketones.The preparation of a useful intermediate in benzomorphinan synthesis has been carried out in o
Photochemical and Thermal Rearrangement of Oxaziridines. Experimental Evidence in Support of the Stereoelectronic Control Theory
Lattes, Armand,Oliveros, Esther,Riviere, Monique,Belzecki, Czeslaw,Mostowicz, Danuta,et al.
, p. 3929 - 3934 (2007/10/02)
The irradiation of an optically pure isomer of a spirooxaziridine, (2R,αS)-6(e)-tert-butyl-2-(α-methylbenzyl)-1,2-oxazaspirooctane, gave a single lactam, (5S,αS)-5-tert-butyl-1-(α-methylbenzyl)hexahydro-2-azepinone.The absolute configurations of thes
