81620-77-1Relevant academic research and scientific papers
Highly Stereoselective Ring Opening Reaction of Tropone Oxime Tosylate with Nucleophiles
Machiguchi, Takahisa,Hasegawa, Toshio,Ohno, Megumi,Kitahara, Yoshio,Funamizu, Makoto,Nozoe, Tetsuo
, p. 838 - 839 (2007/10/02)
The tosylate (1) of tropone oxime undergoes a novel ring-opening reaction under mild conditions with secondary amines, alkoxides, and Grignard reagents affording stereoselectively 6-substituted (1Z,3Z,5Z)-hexa-1,3,5-triene-carbonitriles (2a-h) as sole pro
Palladium-Catalyzed Syntheses of Conjugated Trienes
Kasahara, Akira,Izumi, Taeko,Kudou, Naoto
, p. 704 - 705 (2007/10/02)
Conjugated trienes 3 and 5 have been prepared by the palladium-catalyzed reaction of alkenes 2 with fumaryl chloride (1) and (E)-5-phenyl-2,4-pentadienoyl chloride (4), respectively, in the presence of N-ethylmorpholine.
